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Compared with diesel fuel, FAME is relatively unstable and readily generates acids such as acetic acid and propionic acid. When FAME-blended diesel fuel is used in existing diesel vehicles, it is important to maintain the concentration of FAME-origin acid in the fuel at an appropriately low level to assure vehicle safety. In the present study, the oxidation of diesel fuel containing 5% FAME is investigated. Several kinds of FAMEs were examined, including reagents such as methyl linoleate and methyl linolenate, as well as commercially available products. The level of acid, peroxide, water, and methanol and the pressure of the testing vessel were measured. The result shows that unsaturated FAMEs that have two or more double bonds are unstable. Also, water is generated by oxidation of FAME blended diesel fuel, accelerating corrosion of the terne sheet.

Single cylinder engine testing was carried out to clearly understand the test results of multi-cylinder engines reported by the Diesel WG in JCAP (Japan Clean Air Program) (1), (2), (3) and (4). In this tests, engine specifications such as fuel injection pressure, nozzle hole diameter, turbo-charging pressure, EGR rate, and fuel properties such as 1-, 2-, 3-ring aromatics content, n-,i-paraffins content, and T90 were parametrically changed and their influence on the emissions were studied. PM emission generally increased in each engine condition with increased aromatic contents and T90. In particular, multi ring aromatics brought about large increases in PM regardless of the engine conditions. The influence of fuel properties on NOx emission is smaller than the influence on PM emission. Some other fuels that have various side chain structures of 1-ring aromatics, normal paraffins only and various naphthene contents were also investigated.

For the better understanding of nanoparticles observed on the rode side, adding to the emission test on the chassis dynamometer and engine dynamometer test, possible factors for formation of nanoparticles are investigated. As other possible factors, cold starting of transient test cycle, blow-by gas from heavy duty diesel engine without a positive crankcase ventilation, exhaust braking, and plume mixing of vehicle exhausts were investigated. Nuclei mode particles under the transient test cycles formed during fuel cut period, fuel enrichment period and idling period. Concentration of nuclei mode particles during the idling period are depends on exhaust temperature. The higher exhaust temperature courses the lower number concentration but variation range is within twice. Emission rate of nanoparticles from blow-by gas is one thousandth of tail pipe emissions rate and was found to be negligible.

In the urea SCR system, urea solution is injected by injector installed in the front stage of the SCR catalyst, and NOx can be purified on the SCR catalyst by using NH3 generated by the chemical reaction of urea. NH3 is produced by thermolysis of urea and hydrolysis of isocyanic acid after evaporation of water in the urea solution. But, biuret and cyanuric acid which may cause deposit are sometimes generated by the chemical reactions without generating NH3. Spray behavior and chemical reaction of urea solution injected into the tail-pipe are complicated. The purpose of this study is to reveal the spray behavior and NH3 generation process in the tail-pipe, and to construct the model capable of predicting those accurately. In this report, the impingement spray behavior is clarified by scattered light method in high temperature flow field. Liquid film adhering to the wall and deposit generated after evaporation of water from the liquid film are photographed by the digital camera.

Intermittent Dual-fluid Exhaust Burner (IDEB) has been developed to reduce emissions from methanol fueled vehicles during the warm-up period after a cold start. The IDEB does not need any special fuel injector or blower, and has been built mainly through software modification of an ECU. An FTP mode test while operating an IDEB confirmed that the catalyst temperature was rapidly increased to significantly reduce the emissions to meet a level of ULEV standards.

This paper is an attempt to estimate the traffic demand of private vehicles in the Philippines and Thailand toward 2030. Estimation of road traffic volume is one of the most important elements for determining fuel consumption and emission gas levels. The level of passenger car ownership is still low, but there has been a distinct shift toward passenger cars due to the lack of mass transport. In Asian countries, inspection and maintenance and emission standards are the most important policy measures. The projections of car stock are evaluated as the emissions of PM, CO and NOx by applying these policy measures in the case of Thailand.

The engine in the research is a single cylinder DI diesel using the emission reduction techniques such as high boost, high injection pressure and broad range and high quantity of exhaust gas recirculation (EGR). The study especially focuses on the reduction of particulate matter (PM) under the engine operating conditions. In the experiment the authors measured engine performance, exhaust gases and mass of PM by low sulfur fuel such as 3 ppm and low sulfur lubricant oil such as 0.26%. Then the PM components were divided into soluble organic fraction (SOF) and insoluble organic fraction (ISOF) and they were measured at each engine condition. The mass of SOF was measured from the fuel fraction and lubricant oil fraction by gas chromatography. Also each mass of soot fraction and sulfate fraction was measured as components of ISOF. The experiment was conducted at BMEP = 2.0 MPa as full load condition of the engine and changing EGR rate from 0% to 40 %.

Fuel cell vehicles represent a new system, and their safety has not yet been fully proved comparing with present automobile. Thorough safety evaluation is especially needed for the fuel system, which uses hydrogen as fuel, and the electric system, which uses a lot of electricity. The fuel cell stacks that are to be loaded on fuel cell vehicles generate electricity by reacting hydrogen and oxygen through electrolytic polymer membranes which is very thin. The safety of the fuel and electric systems should also be assessed for any abnormality that may be caused by electrolytic polymer membranes for any reasons. The purpose of our tests is to collect basic data to ultimately establish safety standards for fuel cell stacks. Methanol pool flame exposure tests were conducted on stationary use fuel cell stacks of two 200W to evaluate safety in the event of a fire.

In Biodiesel Fuel Research Working Group(WG) of Japan Auto-Oil Program(JATOP), some impacts of high biodiesel blends have been investigated from the viewpoints of fuel properties, stability, emissions, exhaust aftertreatment systems, cold driveability, mixing in engine oils, durability/reliability and so on. This report is designed to determine how high biodiesel blends affect oil quality through testing on 2005 regulations engines with DPFs. When blends of 10-20% rapeseed methyl ester (RME) with diesel fuel are employed with 10W-30 engine oil, the oil change interval is reduced to about a half due to a drop in oil pressure. The oil pressure drop occurs because of the reduced kinematic viscosity of engine oil, which resulting from dilution of poorly evaporated RME with engine oil and its accumulation, however, leading to increased wear of piston top rings and cylinder liners.

Aldehydes and ketones are known as one of the hazardous air pollutants. Usually, acidified 2,4-dinitrophenylhydrazine (DNPH) solution, or DNPH-impregnated cartridges are used for automotive exhaust carbonyls collection. Then, aldehydes and ketones combined with DNPH are analyzed by HPLC/UV (High Performance Liquid Chromatography/ Ultra Violet Detection). DNPH cartridge is used widely for a good point of the handling although handling of DNPH solution is not so convienient. However, the analytical result of acrolein using DNPH cartridge was known as the low reliability. Acrolein-DNPH is changed to acrolein-DNPH-DNPH in the cartridge with acid atmosphere before extraction. And then, acrorein-DNPH-DNPH is changed to acrorein-DNPH-DNPH-DNPH with an acid atmosphere. As a result of such chemical reaction before extraction, the acrolein-DNPH is detected to low concentration. We found that at the low temperature condition, acrolein-DNPH concentration decrease speed is held down.

If a compressed hydrogen tank for vehicles is filled with hydrogen gas more quickly, the gas temperature in the tank will increase. In this study, we conducted hydrogen gas filling tests using the TYPE 3 and TYPE 4 tanks. During the tests, we measured the temperature of the internal liner surface and investigated its relationship with the gas temperature in the tank. We found that the gas temperature in the upper portion of the TYPE 4 tank rose locally during filling and that the temperature of the internal liner surface near that area also rose, resulting in a temperature higher than the gas temperature at the center of the tank. To keep the maximum temperature in the tank below the designed temperature (85°C) during filling and examine the representative tank internal temperatures, it is important to examine filling methods that can suppress local rises of tank internal temperature.

In order to clarify future automobile technologies and fuel qualities to improve air quality, second phase of Japan Clean Air Program (JCAPII) had been conducted from 2002 to 2007. Predicting improvement in air quality that might be attained by introducing new emission control technologies and determining fuel qualities required for the technologies is one of the main issues of this program. Unregulated material WG of JCAPII had studied unregulated emissions from gasoline and diesel engines. Eight gaseous hydrocarbons (HC), four Aldehydes and three polycyclic aromatic hydrocarbons (PAHs) were evaluated as unregulated emissions. Specifically, emissions of the following components were measured: 1,3-Butadiene, Benzene, Toluene, Xylene, Ethylbenzene, 1,3,5-Trimethyl-benzene, n-Hexane, Styrene as gaseous HCs, Formaldehyde, Acetaldehyde, Acrolein, Benzaldehyde as Aldehydes, and Benzo(a)pyrene, Benzo(b)fluoranthene, Benzo(k)fluoranthene as PAHs.